Si Anode development for very high- capacity Li-ion battery
Subcategory (under Clean Energy): Storage
Technology Readiness Level (TRL): TRL 5 - Large prototype
Technology Outline (Process Description)
Li-ion batteries are the most powerful energy storage technologies having high energy density and long cycle life. Replacing the present commercial anode material, i.e., graphite with Si (properly nanostructured) increases the energy density by 10 times. This high energy density is a result of high intake/removal of Li ions during the charging/discharging of batteries. We have developed a process recipe to grow silicon nanowires (SiNWs) directly on the commercial current collector (Cu), using low-cost catalyst, i.e., tin at a temperature of 400°C. The process requires low processing time of ∼ 30 min. These nanostructured Si (SiNWs) grown directly on copper foils undergo reduced damage during the charging discharging of the batteries as the spaces between the forestof nanowires accommodate the volume change reducing the damage, providing high energy density.
Salient Features/Advantages
- Low processing time of – 30 min
- Facile growth method, does not involve the use of toxic wet chemicals
- Lower growth temperature of ∼ 400°C
- Does not require additional steps of coating and calendaring as in conventional electrodes in batteries
- Tin has been used as the low cost non toxic and abundantly available catalyst material
Key Outcomes
- Controllable growth of SiNW on large area with reproducible results (< 3% variation)
- 250% improvement in capacity retention of SiNW anode at C/5 rate
- 60% of initial capacity retention after 350 cycles in Li ‘half-cell’ configuration ar 1 C rate, (energy density ∼ 260 Wh/kg)
- 97% of initial capacity retention at 1 C current rate in full-cell configuration
- Successful demonstration of coin cell and pouch cell with consumer electronic device
IP Protection details
- Patent filed (Title, national/International): Nil
- Patents Granted: No.: 414337. Dt. 13.12.2022
- Copyrights obtained /progress on commercialisation /Pl. specify connect with industry: A METHOD FOR PRODUCING SILICON NANOWIRES HAVING COMPOSITE STRUCTURE, Indian Patent In talk with HBL PowerSystems Ltd. for technology transfer
Contact details (for more information)
- Nodal Person name: Prof. Rajiv O Dusane
- Email ID: rodusane@iitb.ac.in
- Organisation name (Relevant link/web page): IIT Bombay
Supporting Photographs/Images

Organizations involved in the development (logo/name) Indian Institute of Technology (IIT) Bombay |