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Hydrogen exhaling fuel cell

Subcategory (under Clean Energy): Cross Cutting
Technology Readiness Level (TRL): TRL 4 - Early prototype
Technology Outline (Process Description)

We have designed an unprecedented fuel cell concept exhibiting cathodic hydrogen exhalation capability of anodically inhaled hydrogen, driven by the neutralization energy on decoupling the direct acid–base chemistry. This neutralisation energy can be harvested by reversible H2 redox couple. By coupling a half cell with H2 as the electron donor in an alkaline pH and hydronium ion as the electron acceptor in an acidic pH, we demonstrate a H2 producing H2/ hydronium ion fuel cell with the net cell reaction being the acid base neutralization reaction. Coupling of neutralization energy and reversible H2 redox can be used to spontaneously desalinate saline water while generating electric power by inserting a middle compartment which contains saline water. The desalination chemistry is distinctly different from the desalination in metal ion batteries and flow batteries because the electron donor consumed in the anodic half-cell is regenerated in the cathodic half-cell with the net result being spontaneous water desalination without a net redox reaction and without any water contamination by the discharge products.

Salient Features/Advantages

  • H2 exhaling fuel cell works by harnessing the free energy of acid base neutralization reaction as electromotive force by utilizing the reversible H2 redox couple.
  • This fuel cell can operate as long as there is acid and alkali present in the respective half cells.
  • Desalination of saline water can be spontaneously driven during electric power production without a net redox reaction by interconverting neutralization energy as electrical driving force.

Key Outcomes

  • The fuel exhaling fuel cell can deliver a peak power density of 70 mW/cm2 at a peak current density of 160 mA/cm2 with a cathodic green H2 output of ∼80 mL in 1 hour.
  • The energy benefits from the same fuel stream can at least be doubled by linking the neutralization electrochemical cell in a tandem configuration with a proton exchange membrane fuel cell.
  • To desalinate 1 M NaCl from saline water only 13.6 kJ of energy is required.

IP Protection details

  • Patent filed (Title, national/International): Nil
  • Patents Granted: Nil
  • Copyrights obtained /progress on commercialisation /Pl. specify connect with industry: Nil

Contact details (for more information)

  • Nodal Person name: Muhammed Musthafa O.T.
  • Email ID: musthafa@iiserpune.ac.in
  • Organisation name (Relevant link/web page): IISER, Pune
Supporting Photographs/Images

Organizations involved in the development (logo/name)

IISER, Pune

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