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Bulk-Scale Photocatalytic Green H2-Fuel Production: Establishment of Effective Z-Scheme Mechanism via Simulated Metal Industrial Solid Waste

Subcategory (under Clean Energy): Hydrogen
Technology Readiness Level (TRL): TRL 5 - Large prototype
Technology Outline (Process Description)

A successful construction of a photochemical reactor at the laboratory scale, designed to produce large quantities of Green H2 fuel was achieved, with the assistance of the Z-Scheme charge transfer mechanism established via the employment of simulated metal industrial solid wastes. The demonstration unit, has the ability to generate approximately 45 L of green H2 in an hour, even when utilizing saltwater. This achievement was made possible by employing a pair of 200-watt LED light source. Furthermore, the lab-scale demonstration unit operates at a maximum green H2 production rate of around 1 litre per minute, where it requires a total of 0.4 KW-h of electrical energy. Hence, the as fabricated lab scaled demo unit is capable of effectively producing green hydrogen, even in bulk at a purely cost- effective manner. Assuming the cost of 1 unit of electricity to be ₹10, then to produce 45 L of green hydrogen, an estimated electricity cost of ₹4 will be required. This price scale is completely under the limit, which was put forwarded by Department of Science and Technology, Government of India.

Salient Features/Advantages

  • The boosted Green H2 production rate (maximum: 1 L∙min-1) is the result of augmented Quantum-powered Z-scheme based charge transfer mechanism
  • The synthesis and procurement of the photo-catalyst is very facile and cost-effective, and is even scalable up-to quintal level, without compromising the purity
  • We have designed and assembled the Green H2 production unit, with a straightforward and cost-efficient fashion, so that the capex and opex of the respective industrial-scale technology is minimized
  • The electricity cost of the as produced 45 L of Green H2 will be around ₹ 4, in an hour time scale

Key Outcomes

  • Relatively Enhanced Production rate of “Green” Hydrogen = 45 L∙h-1 with 10 g of Photo-Catalyst
  • Most surprisingly, we have achieved an exceedingly high apparent quantum yield of about 86% as already calibrated through chemical actinometry
  • H2 Flame Test: Hydrogen burns with a nearly invisible pale blue flame, which confirms the very high bulk purity, unlike the electrolyser technology
  • The production methodology employed to produce “Green Hydrogen” can be easily scaled up-to large Industrial Level, with consistent purity

IP Protection details

  • Patent filed (Title, national/International): Bulk Production of Green Hydrogen under Visible Light Irradiation via. Establishment of the Efficient Z-Scheme Based Photo-Catalytic System. Indian Patent Application
  • Patents Granted: Nil
  • Copyrights obtained /progress on commercialisation /Pl. specify connect with industry: The upscaling, large-scale analysis and marketization of the technology will be carried under the expertized supervision of Mr. Khitish Kumar Nayak, Senior Advisor of WellRx Technologies Pvt. Ltd., Haryana and Mr. Onkar Tiwari, Director of Biomimicry Technologies Pvt. Ltd., New Delhi

Contact details (for more information)

  • Nodal Person name: Dr. rer. nat. Somenath Garai
  • Email ID: sgarai@bhu.ac.in
  • Organisation name (Relevant link/web page): Banaras Hindu University, Varanasi
Supporting Photographs/Images

Organizations involved in the development (logo/name)

Green Keplerate Laboratory Department of Chemistry, Institute of Science,

Banaras Hindu University, Varanasi

 

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