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Fabrication of High Energy Density Thin film based on chip Supercapacitor Devices Using Reactive Magnetron Sputtering Technique

Subcategory (under Clean Energy): Storage
Technology Readiness Level (TRL): TRL 2 - Application formulated
Technology Outline (Process Description)

Microsupercapacitors (MSCs) are considered the most promising miniaturized electrochemical energy storage devices in wearable electronics, microsensors, and energy harvesters. The on-chip MSCs are used as a miniaturized power source in these devices because of their small device area, high power density, fast charging-discharging, and long operation life. The prime objective of thisproject is to develop on-chip microsupercapacitors operating in a wide temperature operating range with improved electrochemical performance by exploring novel electrode materials. Many machines and electronic devices such as micro-robots, hybrid electric vehicles, and dielectric elastomers generally require high-voltage power supplies. The low voltage window of the planar on-chip MSCs has been a bottleneck in designing miniature power sources in such microelectronic devices. To achieve a high voltage window, a non-aqueous polymer gel electrolyte having liquid electrolyte (ionic liquid) entrapped in the polymer matrix is utilized. In the present work, novel transition metal nitrides- based interdigitated on-chip MSCs are fabricated by using a shadow mask during the magnetron co-sputtering technique on silicon substrates.

Salient Features/Advantages

  • The on-chip microsupercapacitor (MSC) patterned using interdigitated hard mask during single- step sputtering process is compatible with semiconductor technology and allows scalability to pilot production line for MSCs-related applications. The high voltage on-chip microsupercapacitors can be utilized as miniaturized power sources in many microelectronic devices. The potential applications of microsupercapacitors might include integrations with efficient energy harvesters and wireless communication microelectronics to realize novel self-powering and maintenance-free functional systems.

Key Outcomes

  • The TEABF4/EC/PC/ PVDF gel polymer electrolyte with high ionic conductivity of ~ 10.58 mS.cm-1 is prepared by the solution cast technique. 

  • An exceptionally high voltage window of ~ 3.1 V is achieved in titanium chromium nitride (TiCrN)-based symmetric on-chip MSC higher than any reported metal nitride-based MSC.

  • The on-chip MSC showed an appreciable capacitance of ~500 µF.cm-2 at a current density of 0.07 mA.cm-2 even for a high voltage window of 3.1 V.

  • The on-chip MSC showed energy densities of 0.65 μWh∙cm-2 while maintaining a power density of 169.5 μW.cm-2

IP Protection details

  • Patent filed (Title, national/International): Process initiated
  • Patents Granted: Nil
  • Copyrights obtained /progress on commercialisation /Pl. specify connect with industry: Exploring for commercialization

Contact details (for more information)

  • Nodal Person name: Prof. Ramesh Chandra
  • Email ID: ramesh.chandra@ic.iitr.ac.in
  • Organisation name (Relevant link/web page): Indian Institute of Technology Roorkee
Supporting Photographs/Images

Organizations involved in the development (logo/name)

Indian Institute of Technology Roorkee

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