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Integrated CO2 absorption and conversion to methanol in slurry phase reactors using metal complexes as catalyst

Subcategory (under Clean Energy): CCU
Technology Readiness Level (TRL): TRL 4 -5
Technology Outline (Process Description)
  • The objective is to propose a one-pot CO2 capture and conversion to methanol at milder process conditions compared to the industrial methanol production from syngas by IITD:
  • Rational design of a system of mixtures of polyamines and ionic liquids, having negligible volatility, will be able to absorb CO2 from industrial process streams.
  • Detailed reaction kinetics and mechanism in such a reaction system will be first established in a lab scale batch slurry reactor and then lab scale continuous flow reactor.
  • The possibility of extrapolating small diameter behavior to larger ones for a continuous integrated CO2 to methanol process in a scaled-up Slurry Bubble column reactor will be explored and investigated.
  • The critical issues in such an extrapolation pertaining to mixing and hydrodynamic characteristics, establishing reliable similarity criteria that would result in similar mixing and hydrodynamics and hence transport and performance in two different scales will be attempted to be solved.
  • Continuous high-throughput lab-scale slurry phase reactor investigations of the CO2 capture and methanol synthesis reaction for a long time-on-stream to assess the stability of the system before scale-up.

Salient Features/Advantages

  • Carbon capture impacts throughout the country.

Key Outcomes

  • Project team has developed a Lab-scale batch slurry phase reactor which has been successfully installed and demonstrated with integrated CO2 capture and conversion Technology for CO2 to methanol using innovative catalysts.

IP Protection details

  • Patent filed (Title, national/International): (1) System and Process for Pre-combustion, Post- combustion and Direct Air Capture of Carbon dioxide. (2) A process for low temperature CO2 capture and consecutive conversion to methanol in a three-phase catalytic reactor system. (3) Process for integrated CO2 capture and conversion to renewable gasoline blended fuel in a multi-phase reactor
  • Patents Granted: Nil
  • Copyrights obtained /progress on commercialisation /Pl. specify connect with industry: Nil

Contact details (for more information)

Supporting Photographs/Images

Organizations involved in the development (logo/name)

Indian Institute Of Technology (IIT) Delhi

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